monkey spanners
05-12-2011, 08:57 PM
Read this in this months fridge mag, trimethyl aluminium is whats made when the methyl chloride in fake R134a reacts with aluminium in compressor etc, it goes bang when when it meets air. Three engineers have been killed so far due to stuff going pop while being fixed. These were reefer unit but some car ac systems have been affected as well. The methyl chloride will eat hoses etc too and turns oil into goo....
Be careful where you get your gas!
install monkey
05-12-2011, 10:19 PM
ref from wikipedia
TrimethylaluminiumFrom Wikipedia, the free encyclopedia
(Redirected from Trimethyl aluminium (http://www.refrigeration-engineer.com/w/index.php?title=Trimethyl_aluminium&redirect=no))
Jump to: navigation (http://www.refrigeration-engineer.com/forums/#mw-head), search (http://www.refrigeration-engineer.com/forums/#p-search)
Trimethylaluminium
http://upload.wikimedia.org/wikipedia/commons/thumb/4/43/Trimethylaluminium-3D-balls.png/200px-Trimethylaluminium-3D-balls.png (http://www.refrigeration-engineer.com/wiki/File:Trimethylaluminium-3D-balls.png)
IUPAC name (http://www.refrigeration-engineer.com/wiki/International_Union_of_Pure_and_Applied_Chemistry_nomenclature)[hide] (javascript:toggleNavigationBar(1);)
trimethylalumane
Other names[hide] (javascript:toggleNavigationBar(2);)
Trimethylaluminium; aluminium trimethyl
Identifiers
CAS number (http://www.refrigeration-engineer.com/wiki/CAS_registry_number)
75-24-1 (http://www.commonchemistry.org/ChemicalDetail.aspx?ref=75-24-1) http://upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.pngY
PubChem (http://www.refrigeration-engineer.com/wiki/PubChem)
16682925 (http://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=16682925)
ChemSpider (http://www.refrigeration-engineer.com/wiki/ChemSpider)
10606585 (http://www.chemspider.com/10606585) http://upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.pngY
Jmol (http://www.refrigeration-engineer.com/wiki/Jmol)-3D images
Image 1 (http://chemapps.stolaf.edu/jmol/jmol.php?model=C%5BAl%5D%28C%29C)
SMILES (http://www.refrigeration-engineer.com/wiki/Simplified_molecular_input_line_entry_specification)
[show] (javascript:toggleNavigationBar(3);)
C[Al](C)C
InChI (http://www.refrigeration-engineer.com/wiki/International_Chemical_Identifier)
[show] (javascript:toggleNavigationBar(4);)
InChI=1S/3CH3.Al/h3*1H3; http://upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.pngY
Key: JLTRXTDYQLMHGR-UHFFFAOYSA-N http://upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.pngY
InChI=1/3CH3.Al/h3*1H3;/rC3H9Al/c1-4(2)3/h1-3H3
Key: JLTRXTDYQLMHGR-MZZUXTGEAJ
Properties
Molecular formula (http://www.refrigeration-engineer.com/wiki/Chemical_formula)
C6H18Al2
Molar mass (http://www.refrigeration-engineer.com/wiki/Molar_mass)
144.18 g/mol
Appearance
Colorless liquid
Density (http://www.refrigeration-engineer.com/wiki/Density)
0.752 g/mL
Melting point (http://www.refrigeration-engineer.com/wiki/Melting_point)
15 °C
Boiling point (http://www.refrigeration-engineer.com/wiki/Boiling_point)
125 °C
Hazards
Main hazards (http://www.refrigeration-engineer.com/wiki/Worker_safety_and_health)
Pyrophoric
NFPA 704 (http://www.refrigeration-engineer.com/wiki/NFPA_704)
http://upload.wikimedia.org/wikipedia/commons/thumb/6/6f/NFPA_704.svg/75px-NFPA_704.svg.png (http://www.refrigeration-engineer.com/wiki/File:NFPA_704.svg)
4
3
3
W
http://upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.pngY (verify) (http://en.wikipedia.org/w/index.php?title=Special:ComparePages&rev1=399170565&page2=Trimethylaluminium) (what is: (http://www.refrigeration-engineer.com/wiki/Wikipedia:WikiProject_Chemicals/Chembox_validation) http://upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/10px-Yes_check.svg.pngY/http://upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/10px-X_mark.svg.pngN?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) (http://www.refrigeration-engineer.com/wiki/Standard_state)
Infobox references (http://www.refrigeration-engineer.com/wiki/Wikipedia:Chemical_infobox#References)
Trimethylaluminium is the chemical compound (http://www.refrigeration-engineer.com/wiki/Chemical_compound) with the formula Al (http://www.refrigeration-engineer.com/wiki/Aluminium)2(CH3 (http://www.refrigeration-engineer.com/wiki/Methyl))6, abbreviated as Al2Me6, (AlMe3)2 or the abbreviation TMA. This pyrophoric (http://www.refrigeration-engineer.com/wiki/Pyrophoric), colorless liquid is an industrially important organoaluminium (http://www.refrigeration-engineer.com/wiki/Organoaluminium) compound. It evolves white smoke (aluminium oxides) when the vapor is released into the air.
Contents [hide (http://www.refrigeration-engineer.com/forums/#)]
1 Structure and bonding (http://www.refrigeration-engineer.com/forums/#Structure_and_bonding)
2 Synthesis and applications (http://www.refrigeration-engineer.com/forums/#Synthesis_and_applications)
3 Semiconductor grade TMA (http://www.refrigeration-engineer.com/forums/#Semiconductor_grade_TMA)
4 References (http://www.refrigeration-engineer.com/forums/#References)
5 External links (http://www.refrigeration-engineer.com/forums/#External_links)
[edit (http://www.refrigeration-engineer.com/w/index.php?title=Trimethylaluminium&action=edit§ion=1)] Structure and bondingAl2Me6 exists as a dimer (http://www.refrigeration-engineer.com/wiki/Dimer_(chemistry)), analogous in structure and bonding to diborane (http://www.refrigeration-engineer.com/wiki/Diborane). As with diborane, the metalloids are connected by a 3-center-2-electron bond (http://www.refrigeration-engineer.com/wiki/3-center-2-electron_bond): the shared methyl groups bridge between the two aluminium atoms. The Al-C(terminal) and Al-C(bridging) distances are 1.97 and 2.14 Å, respectively.[1] (http://www.refrigeration-engineer.com/forums/#cite_note-0) The carbon atoms of the bridging methyl groups are each surrounded by five neighbors: three hydrogen atoms and two aluminium atoms. The methyl groups interchange readily intramolecularly and intermolecularly.
3-Centered-2-electron bonds are an utterance of "electron-deficient" molecules and tend to reactions with Lewis bases (http://www.refrigeration-engineer.com/wiki/Lewis_base) that would give products consisting of 2-centered-2-electron bonds. For example upon treatment with amines gives adducts (http://www.refrigeration-engineer.com/wiki/Adduct) R3N-AlMe3. Another reaction that gives products that follow the octet rule (http://www.refrigeration-engineer.com/wiki/Octet_rule) is the reaction of Al2Me6 with aluminium trichloride (http://www.refrigeration-engineer.com/wiki/Aluminium_trichloride) to give (AlMe2Cl)2.
The species AlMe3, which would feature an aluminium (http://www.refrigeration-engineer.com/wiki/Aluminium) atom (http://www.refrigeration-engineer.com/wiki/Atom) bonded to three methyl (http://www.refrigeration-engineer.com/wiki/Methyl) groups is unknown. VSEPR Theory (http://www.refrigeration-engineer.com/wiki/VSEPR_Theory) predicts that such a molecule would have idealized threefold symmetry (http://www.refrigeration-engineer.com/wiki/Symmetry_group), as observed in BMe3.
[edit (http://www.refrigeration-engineer.com/w/index.php?title=Trimethylaluminium&action=edit§ion=2)] Synthesis and applicationsTMA is prepared via a two-step process that can be summarized as follows:
2 Al + 6 CH3Cl (http://www.refrigeration-engineer.com/wiki/Methyl_chloride) + 6 Na → Al2(CH3)6 + 6 NaClTMA is mainly used for the production of methylaluminoxane (http://www.refrigeration-engineer.com/wiki/Methylaluminoxane), an activator for Ziegler-Natta catalysts (http://www.refrigeration-engineer.com/wiki/Ziegler-Natta_catalyst) for olefin polymerisation. TMA is also employed as a methylation agent. Tebbe's reagent (http://www.refrigeration-engineer.com/wiki/Tebbe%27s_reagent), which is used for the methylenation of esters (http://www.refrigeration-engineer.com/wiki/Ester) and ketones (http://www.refrigeration-engineer.com/wiki/Ketone), is prepared from TMA. TMA is often released from sounding rockets (http://www.refrigeration-engineer.com/wiki/Sounding_rockets) as a tracer in studies of upper atmospheric wind patterns.
TMA is also used in semiconductor fabrication to grow thin film, high-k dielectrics (http://www.refrigeration-engineer.com/wiki/Dielectric) such as Al2O3 via the processes of Chemical Vapor Deposition (http://www.refrigeration-engineer.com/wiki/Chemical_Vapor_Deposition) or Atomic Layer Deposition (http://www.refrigeration-engineer.com/wiki/Atomic_Layer_Deposition).
TMA forms a complex with the tertiary amine (http://www.refrigeration-engineer.com/wiki/Tertiary_amine) DABCO (http://www.refrigeration-engineer.com/wiki/DABCO), which is safer to handle than TMA itself.[2] (http://www.refrigeration-engineer.com/forums/#cite_note-1)
In combination with Cp2ZrCl2 (zirconocene dichloride), the (CH3)2Al-CH3 adds "across" alkynes to give vinyl aluminium species that are useful in organic synthesis (http://www.refrigeration-engineer.com/wiki/Organic_synthesis) in a reaction known as carboalumination.[3] (http://www.refrigeration-engineer.com/forums/#cite_note-2)
[edit (http://www.refrigeration-engineer.com/w/index.php?title=Trimethylaluminium&action=edit§ion=3)] Semiconductor grade TMATMA is the preferred metalorganic (http://www.refrigeration-engineer.com/wiki/Metalorganic) source for metalorganic vapour phase epitaxy (http://www.refrigeration-engineer.com/wiki/Metalorganic_vapour_phase_epitaxy) (MOVPE (http://www.refrigeration-engineer.com/wiki/MOVPE)) of aluminium-containing compound semiconductors (http://www.refrigeration-engineer.com/wiki/Compound_semiconductor), such as AlAs (http://www.refrigeration-engineer.com/wiki/Aluminium_arsenide), AlN (http://www.refrigeration-engineer.com/wiki/Aluminium_nitride), AlP (http://www.refrigeration-engineer.com/wiki/Aluminium_phosphide), AlSb (http://www.refrigeration-engineer.com/wiki/Aluminium_antimonide), AlGaAs (http://www.refrigeration-engineer.com/wiki/Aluminium_gallium_arsenide), AlInGaAs (http://www.refrigeration-engineer.com/w/index.php?title=Aluminium_indium_gallium_arsenide&action=edit&redlink=1), AlInGaP (http://www.refrigeration-engineer.com/w/index.php?title=Aluminium_indium_gallium_phosphide&action=edit&redlink=1), AlGaN (http://www.refrigeration-engineer.com/wiki/Aluminium_gallium_nitride), AlInGaN (http://www.refrigeration-engineer.com/w/index.php?title=Aluminium_indium_gallium_nitride&action=edit&redlink=1), AlInGaNP (http://www.refrigeration-engineer.com/w/index.php?title=Aluminium_indium_gallium_nitride_phosphide&action=edit&redlink=1) etc. Criteria for TMA quality focus on (a) elemental impurites, (b) oxygenated and organic impurities.
[edit (http://www.refrigeration-engineer.com/w/index.php?title=Trimethylaluminium&action=edit§ion=4)] References
^ (http://www.refrigeration-engineer.com/forums/#cite_ref-0) Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. ISBN 0-12-352651-5 (http://www.refrigeration-engineer.com/wiki/Special:BookSources/0123526515).
^ (http://www.refrigeration-engineer.com/forums/#cite_ref-1) Biswas, K.; Prieto, O.; Goldsmith, P. J.Woodward, S. (2005). "Remarkably Stable (Me3Al)2DABCO and Stereoselective Nickel-Catalyzed AlR3 (R = Me, Et) Additions to Aldehydes". Angewandte Chemie International Edition (http://www.refrigeration-engineer.com/wiki/Angewandte_Chemie_International_Edition) 44 (15): 2232–2234. doi (http://www.refrigeration-engineer.com/wiki/Digital_object_identifier):10.1002/anie.200462569 (http://dx.doi.org/10.1002%2Fanie.200462569). PMID (http://www.refrigeration-engineer.com/wiki/PubMed_Identifier) 15768433 (http://www.ncbi.nlm.nih.gov/pubmed/15768433).
^ (http://www.refrigeration-engineer.com/forums/#cite_ref-2) Negishi, E.; Matsu****a, H., "Palladium-Catalyzed Synthesis of 1,4-Dienes by Allylation of Alkenyalane: α-Farnesene [1,3,6,10-Dodecatetraene, 3,7,11-trimethyl-]" (http://www.orgsyn.org/orgsyn/orgsyn/prepContent.asp?prep=cv7p0245), Org. Synth. (http://www.refrigeration-engineer.com/wiki/Organic_Syntheses), http://www.orgsyn.org/orgsyn/orgsyn/prepContent.asp?prep=cv7p0245 ; Coll. Vol. 7: 245
[edit (http://www.refrigeration-engineer.com/w/index.php?title=Trimethylaluminium&action=edit§ion=5)] External links
Informative commercial link to Trimethylaluminum and other metalorganics. (http://electronicmaterials.rohmhaas.com/products/Default.asp?product=Trimethylaluminum)
Interactive Vapor Pressure Chart for metalorganics (http://electronicmaterials.rohmhaas.com/businesses/micro/metalorganics/vapor.asp?caid=291).
monkey spanners
05-12-2011, 10:23 PM
Found a link to the article,
http://www.acr-news.com/news/news.asp?id=2641&src=tw
It go bang!
A few questions:
1. How does a service technician determine beforehand whether an unknown system is safe to work on?
2. What are safe working procedures to remove the hazardous material, & make the system safe?
3. If a system is determined to be contaminated, what happens - is it scrapped?
4. If scrapped, should it be made safe first?
nevgee
11-12-2011, 11:47 AM
I read that the real danger is due to the fact that trimethyl aluminium combusts instantaneously (explosively) on contact with air.
Apparently it is a liquid and generally sits in the crankcase with the oil! :eek: If no oxygen gets to the substance everything would appear to remain safe but for the fact this stuff creates havac if mixed with POe oil and generally becomes a seriously aggressive kid on the block by destroying everything it touches, especially seals.
Sounds very much like a substitute for Alien spit.:eek:
That makes a suspected contaminated system one really hot potato to handle. safe bet would be to call the Bomb squad and walk (run) away.;)
It has been suggested a practical way to remove the substance would be to pierce the base of the crankcase and use OFN to blow (no pun intended) the contaminated oil out into a container of water. Sounds simple enough but I wouldn't particularly wish to be the one to try it.
Upside is that you do not need to have an "F" Gas qualification to handle Methyl Chloride or its bi products. So leave it to the cowboys to deal with.:D:D
Lodiev
12-12-2011, 09:13 AM
This is no joke.
i think the big question is:HOW DO U DETERMINE IF THE SYSTEM U HAVE TO WORK ON ARE CONTAMINATED?
Hope this will teach the gas buyers to make sure that they buy quality gas and not just the cheapies from China.
Cambridge Refrigeration Technology is working on finding solutions to the problem. Their latest report can be found here:
http://www.ttclub.com/fileadmin/uploads/tt-club/Publications___Resources/TT_Talk/Cambridge%20Refrigeration%20Technology%20-%20Revised%20Info%20regarding%20Counterfeir%20Refrigerant.pdf
Powered by vBulletin® Version 4.2.1 Copyright © 2024 vBulletin Solutions, Inc. All rights reserved.